Do Your Best and Forget The Rest. PLAY TO WIN.

If you get the message that there's an issue with your computer which makes you blocked from all VAC Servers on CS:GO then the solution to fixing that (which worked for me) is to:

>Exit Steam
>Run Steam as Administrator for PC from the Steam file
>Go Back in Steam
>Go into CS:GO

Then after these actions, your CS:GO should work normally.
Your Welcome, if this helps you out in any way. If this doesn't work for you than sorry for the disappointment.